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Initial consonant cluster /ʃm/
From Teflpedia
/ʃm/ is an initial consonant cluster that occurs marginally in English.
Where it does occur, it tends to be in German-to-English loans or Yiddish-to-English loans. The spelling is schm, like schmaltz, schmo, schmuck, schmooze, schmeltz[1] and few other words. It also occurs in some surnames of German origin, e.g. Schmidt.
English phonotactics naturally prefers initial consonant cluster /sm/ in such positions.
Though this exists, it’s probably not worth teaching to EFL students unless a word like this comes up.